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Genesis 4:15

Genesis 4:15 (ESV)
Then the Lord said to him, "Not so! If anyone kills Cain, vengeance shall be taken on him sevenfold." And the Lord put a mark on Cain, lest any who found him should attack him.

Genesis 4:5

Genesis 4:5 (ESV)
but for Cain and his offering he had no regard. So Cain was very angry, and his face fell.